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Article Details

Article Details

  • Article Code : FIRAT-AKADEMI-9249-5544
  • Article Type : Araştırma Makalesi
  • Publication Number : 1A0481
  • Page Number : 42-53
  • Doi : 10.12739/NWSA.2022.17.4.1A0481
  • Abstract Reading : 456
  • Download : 137
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Issue Details

  • Year : 2022
  • Volume : 17
  • Issue : 4
  • Number of Articles Published : 2
  • Published Date : 1.10.2022

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Dergi Kapağı
Engineering Sciences

Serial Number : 1A
ISSN No. : 1308-7231
Release Interval (in a Year) : 4 Issues

Ferhat TÜRKER1 , Yetkin GÖK2 , Aydın AKTAS3

Keywords
Sulu ortam, N-heterosiklik karbenler, Paladyum kompleksi, Sonogashira reaksiyonu, Trifenilfosfin,

PALLADIUM-BASED COMPLEXES BEARING N-HETEROCYCLIC CARBENE (NHC) AND TRIPHENYLPHOSPHINE (PPH3) LIGANDS: SYNTHESIS, CHARACTERIZATION, AND ITS APPLICATION ON SONOGASHIRA CROSS-COUPLING REACTIONS IN AQUEOUS MEDIA

Ferhat TÜRKER1 , Yetkin GÖK2 , Aydın AKTAS3

Herein, we reported the synthesis of a new series of Pd-based complexes bearing N-heterocyclic carbene (NHC) and triphenylphosphine (PPh3) ligands. These complexes have been prepared from the (NHC)Pd(II)(pyridine) complexes and PPh3. All (NHC)Pd(II)PPh3 complexes have been characterized by using 1H NMR, 13C {1H}NMR, 31P {1H}NMR, and FTIR spectroscopy and elemental analysis technique. Here, as a result of low catalyst [(NHC)Pd(II)PPh3] loading (0.01 mmol), acetylene derivatives with various functional groups were synthesized from the coupling of phenylacetylene with various aryl bromides in the aqueous medium.

Keywords
Aqueous Medium, N-heterocyclic Carbenes, Palladium Complex, Sonogashira Reactions, Triphenylphosphine,

Details
   

Authors

Ferhat TÜRKER (1)

ferhatturker5@gmail.com | 0000-0001-5822-2683

Yetkin GÖK (2)

İnönü Üniversitesi
yetkin.gok@inonu.edu.tr | 0000-0003-3993-7733

Aydın AKTAS (3) (Corresponding Author)
İnönü Üniversitesi
aydin.aktas@inonu.edu.tr | 0000-0001-8496-6782

Supporting Institution

 : İnönü Üniversitesi

Project Number

 : FYL-2019-1446

Thanks

 : The authors thank the İnönü University Faculty of Science Department of Chemistry for the spectroscopy data and characterization of compounds. This study was financially supported by Inonu University Research Fund. Project Code: FYL-2019-1446.
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