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Article Details

  • Article Code : NWSA-1609-919
  • Article Type : Araştırma Makalesi
  • Publication Number : 3A0022
  • Page Number : 45-51
  • Doi : 10.12739/
  • Abstract Reading : 1049
  • Download : 116
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Issue Details

  • Year : 2010
  • Volume : 5
  • Issue : 2
  • Number of Articles Published : 2
  • Published Date : 1.04.2010

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Physical Sciences

Serial Number : 3A
ISSN No. : 1308-7304
Release Interval (in a Year) : 4 Issues

YENİ BİR KSANTATIN SENTEZİ VE KOBALT, NİKEL, BAKIR KOMPLEKSLERİNİN KARAKTERİZASYONU

Ahmet Orhan GÖRGÜLÜ 1

1,3-di(4-metilpiperidino)propan-2-ol (ROH) 1,3- dikloropropan-2-ol ile 4-metilypiperidinin reaksiyonundan sentezlendi. Potasyum 1,3-di(4-metilpiperidino)propan-2-O-ksantat (ROCSSK) 1,3-di(4-metilpiperidino) propan-2-ol (ROH) ile karbon disülfür ve metalik potasyumun reaksiyona sokulmasyyla elde edildi. Bütün ürünler genel olarak yüksek verimle elde edildi. Co(II), Ni(II) ve Cu(I) ksantat kompleksleri su ortamynda,[CoL2(H2O)2], [NiL2(H2O)2].2H2O ve [CuL].2H2O olarak sentezlendi. Yeni ksantat ligandy ve kompleksleri, FT-IR, 1H ve 13C NMR spektroskopisi, elementel analiz, magnetik süsseptibilite ve TGA teknikleri ileyapylary aydynlatyldy.

Keywords
Co(II) kompleksleri, Ni(II) kompleksleri, Cu(I) kompleksleri, Ksantat, NMR,

THE SYNTHESIS, CHARACTERIZATION OF A NOVEL XANTHATE COMPLEXES OF COBALT NICKEL AND COPPER

Ahmet Orhan GÖRGÜLÜ 1

1,3-di(4-methylpiperidino)propan-2-ol (ROH) was synthesized from the reaction of 1,3-dichloropropan-2-ol with 4-methlypiperidine. Potassium 1,3-di(4-methylpiperidino)propan-2-O-xanthate (ROCSSK) was obtained from the reaction of 1,3-di(4-methylpiperidino)propan-2-ol (ROH) with carbon disulfide and metallic potassium. All products were generally obtained in high yields. Xanthate complexes of Co(II), Ni(II) and Cu(I) was synthesized in the medium water as [CoL2(H2O)2], [NiL2(H2O)2].2H2O and [CuL].2H2O. The novel xanthate ligand and its complexes were defined by FTIR, 1H and 13C NMR spectroscopies, elemental analyses, magnetic susceptibility and TGA techniques.

Keywords
Co(II) complexes, Ni(II) complexes, Cu(I) complexes,, Xanthate, NMR,

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Ahmet Orhan GÖRGÜLÜ (1) (Corresponding Author)

FIRATÜNİVERSİTESİ
aogorgulu@firat.edu.tr

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