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Article Details

  • Article Code : FIRAT-AKADEMI-12745-5728
  • Article Type : Araştırma Makalesi
  • Publication Number : 2A0206
  • Page Number : 60-68
  • Doi : 10.12739/NWSA.2025.20.2.2A0206
  • Abstract Reading : 90
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Issue Details

  • Year : 2025
  • Volume : 20
  • Issue : 2
  • Number of Articles Published : 2
  • Published Date : 1.04.2025

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Dergi Kapağı
Technological Applied Sciences

Serial Number : 2A
ISSN No. : 1308-7223
Release Interval (in a Year) : 4 Issues

AYÇİÇEĞİ KÜSPESİNİN PİROLİZİNDE BORİK ASİTİN BİYOÜRÜNLERE ETKİSİ

İkbal Ay Keçeli1 , Bahattin Aydınlı2

Bu çalışmada, ayçiçeği küspesi gibi endüstriyel tarımsal atıkların değerlendirilmesiyle sürdürülebilir bir yöntem olan piroliz işlemi sırasında borik asit katkısının biyoürün verimliliği üzerindeki etkileri araştırılmıştır. Deneysel çalışmalarda karşılaştırma açısından katkısız biyokütle ve %6.6 oranında borik asit katkısı uygulanmış ayçiçeği küspesi numuneleri 400, 450, 500 ve 550?°C sıcaklıklarda pirolize edilmiştir. Elde edilen katı, sıvı ve gaz ürünler kantitatif olarak değerlendirilmiştir. Bulgular, borik asit katkısının özellikle düşük sıcaklıklarda biyokömür verimini artırdığını, yüksek sıcaklıklarda ise sıvı ve gaz ürünlerin oranını azalttığını göstermiştir. Borik asit katkısının piroliz verimi açısından sınırlayıcı etkiler gösterebildiği gözlenmiştir. Çalışma, borik asit katkısının piroliz sürecini ve sonucunu etkilemesi açısından başka çalışmalara önemli bir temel oluşturmaktadır.

Keywords
Biyokütle, Piroliz, Borik Asit, Katalizör, Biyoürün,

EFFECT OF BORİC ACİD ON BİOPRODUCTS İN PYROLYSİS OF SUNFLOWER MEAL

İkbal Ay Keçeli1 , Bahattin Aydınlı2

This study investigated the effects of boric acid addition on bioproduct efficiency during the pyrolysis process, which is a sustainable method, by evaluating industrial agricultural wastes such as sunflower meal. In the experimental studies, for comparison, unmixed biomass and sunflower meal samples with 6.6% boric acid addition were pyrolyzed at 400, 450, 500, and 550°C. The solid, liquid, and gaseous products obtained were evaluated quantitatively. The findings showed that boric acid addition increased biochar yield, especially at low temperatures, while it decreased the ratio of liquid and gaseous products at high temperatures. It was observed that boric acid addition may have limiting effects in terms of pyrolysis efficiency. The study provides an important basis for other studies in terms of the effect of boric acid addition on the pyrolysis process and result.

Keywords
Biomass, Pyrolysis, Boric Acid, Catalyst, Bioproduct,

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Authors

İkbal Ay Keçeli (1) (Corresponding Author)
Çankırı Karatekin Üniversitesi
iay@karatekin.edu.tr | 0000-0002-1125-7552

Bahattin Aydınlı (2)

baydinli@kastamonu.edu.tr | 0000-0002-6525-4162

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References
[1] Aydinli, B. and Caglar, A., (2012). The investigation of the effects of two different polymers and three catalysts on pyrolysis of hazelnut shell. Fuel Processing Technology, 93(1):1-7.

[2] Zhang, K., (2025). A review of biomass energy: Comparison of utilization methods and future prospects. E3S Web of Conferences.

[3] Semerci, A. and Durmuş, E., (2021). Türkiye ‘de Yağlık Ayçiçeği Üretiminin Analizi. Turkish Journal of Agriculture-Food Science and Technology, 9(1):56-62.

[4] Cerit, İ., (2025). Mikrodalga destekli ekstraksiyon ve in vitro sindirimin Ayçiçek posası ekstraktının fenolik içerik ve antioksidan aktivitesine etkisi. Gıda, 50(1):116-130.

[5] Kocabaş, T., (2021). Trakya Bölgesi'nde üretilen ayçiçeği küspelerinin kimyasal kalitesinin belirlenmesi üzerine bir araştırma.

[6] Grahovac, N., Luzaic, T., Zivancev, D., Stojanovic, Z., Durovic, A., Romanic, R., ... and Miklic, V., (2024). Assessing nutritional characteristics and bioactive compound distribution in seeds, oil, and cake from confectionary sunflowers cultivated in Serbia. Foods, 13(12):1882.

[7] Mohan, D., Pittman, C.U., and Steele, P.H., (2006). Pyrolysis of wood/biomass for bio-oil: A critical review. Energy & Fuels, 20(3):848-889.

[8] Aydinli, B. and Caglar, A., (2012). The investigation of the effects of two different polymers and three catalysts on pyrolysis of hazelnut shell. Fuel Processing Technology, 93(1):1-7.

[9] Bridgwater, A.V., (2012). Review of fast pyrolysis of biomass and product upgrading. Biomass and Bioenergy, 38:68-94.

[10] Li, W., Wang, D., Zhu, Y., Chen, J., Lu, Y., Li, S., Zheng, Y., and Zheng, Z., (2020). Efficient ex-situ catalytic upgrading of biomass pyrolysis vapors to produce methylfurans and phenol over bio-based activated carbon. Biomass & Bioenergy.

[11] Cheng, X. and Wang, B., (2017). Yield, Composition, and Property of Biochar Obtained from the Two-Step Pyrolysis of Rice Husk Impregnated with Boric Acid. Energies, 10(11):1814.

[12] Wang, J., Wang, L., and Li, Y., (2024). Investigating the catalytic influence of boron on Ni-Co/Ca catalysts for improved syngas generation from rice straw pyrolysis. Molecules.

[13] Mohamed, B.A., Ellis, N., Kim, C.S., and Bi, X., (2020). Synergistic effects of catalyst mixtures on biomass catalytic pyrolysis. Frontiers in Bioengineering and Biotechnology.

[14] Dong, Z., Yang, H., Liu, Z., Chen, P., Chen, Y., Wang, X., and Chen, H., (2021). Effect of boron-based additives on char agglomeration and boron-doped carbon microspheres structure from lignin pyrolysis. Fuel.

[15] Wang, Y., Liu, M., Zhao, X., Cao, D., Guo, T., and Yang, B., (2018). Insights into heterogeneous catalysis of peroxymonosulfate activation by boron-doped ordered mesoporous carbon. Carbon, 135:238-247.

[16] Hou, X., Li, Z., and Zhang, Z., (2021). Selectively producing acetic acid via boric acid-catalyzed fast pyrolysis of woody biomass. Catalysts, 11(4):494.

[17] Wang, Q., Li, J., and Winandy, J.E., (2004). Chemical mechanism of fire retardance of boric acid on wood. Wood science and technology, 38:375-389.

[18] Hwang, H.T., Greenan, P., Kim, S.J., and Varma, A., (2013). Effect of boric acid on thermal dehydrogenation of ammonia borane: H2 yield and process characteristics. AIChE Journal, 59(9):3359-3364.

[19] Lim, X.Y. and Andresen, J.M., (2011). Pyro-catalytic deoxygenated bio-oil from palm oil empty fruit bunch and fronds with boric oxide in a fixed-bed reactor. Fuel Processing Technology, 92(9):1905–1911.

[20] Wystalska, K., Malinska, K., Wlodarczyk, R., and Chajczyk, O., (2018). Effects of pyrolysis parameters on the yield and properties of biochar from pelletized sunflower husk. E3S Web of Conferences, 44:00197.

[21] Di Blasi, C., Branca, C., and Galgano, A., (2007). Flame retarding of wood by impregnation with boric acid – Pyrolysis products and char oxidation rates. Polymer Degradation and Stability, 92(5):893–902.