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Fırat Akademi Samsun-Türkiye
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1,3-di(4-metilpiperidino)propan-2-ol (ROH) 1,3- dikloropropan-2-ol ile 4-metilypiperidinin reaksiyonundan sentezlendi. Potasyum 1,3-di(4-metilpiperidino)propan-2-O-ksantat (ROCSSK) 1,3-di(4-metilpiperidino) propan-2-ol (ROH) ile karbon disülfür ve metalik potasyumun reaksiyona sokulmasyyla elde edildi. Bütün ürünler genel olarak yüksek verimle elde edildi. Co(II), Ni(II) ve Cu(I) ksantat kompleksleri su ortamynda,[CoL2(H2O)2], [NiL2(H2O)2].2H2O ve [CuL].2H2O olarak sentezlendi. Yeni ksantat ligandy ve kompleksleri, FT-IR, 1H ve 13C NMR spektroskopisi, elementel analiz, magnetik süsseptibilite ve TGA teknikleri ileyapylary aydynlatyldy.
Keywords
Co(II) kompleksleri,
Ni(II) kompleksleri,
Cu(I) kompleksleri,
Ksantat,
NMR,
1,3-di(4-methylpiperidino)propan-2-ol (ROH) was synthesized from the reaction of 1,3-dichloropropan-2-ol with 4-methlypiperidine. Potassium 1,3-di(4-methylpiperidino)propan-2-O-xanthate (ROCSSK) was obtained from the reaction of 1,3-di(4-methylpiperidino)propan-2-ol (ROH) with carbon disulfide and metallic potassium. All products were generally obtained in high yields. Xanthate complexes of Co(II), Ni(II) and Cu(I) was synthesized in the medium water as [CoL2(H2O)2], [NiL2(H2O)2].2H2O and [CuL].2H2O. The novel xanthate ligand and its complexes were defined by FTIR, 1H and 13C NMR spectroscopies, elemental analyses, magnetic susceptibility and TGA techniques.
Keywords
Co(II) complexes,
Ni(II) complexes,
Cu(I) complexes,,
Xanthate,
NMR,
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